Asphaltenes, heavy oils, and petroleomics by Oliver C Mullins; et al

By Oliver C Mullins; et al

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All predictions are confirmed; many of which are presented in other chapters in this book. Asphaltene Molecular Size and Weight 27 All asphaltenes are shown to share certain key characteristics. Some important differences are noted particularly between coal and petroleum asphaltenes providing a stringent test platform for ideas advanced in this chapter. High temperature hydrotreatment samples are shown to behave as expected based on the coal and petroleum results lending credence to interpretations herein.

Conf. Paper, 10036. F. (1990). ACS Div. Pet. Chem. Preprint, 35, 314. 2 Asphaltene Molecular Size and Weight by Time-Resolved Fluorescence Depolarization Henning Groenzin and Oliver C. Mullins 1. 1. Overview The most important attribute of any chemical compound is its elemental constituents. There is, fortunately, no uncertainty about the elemental composition of asphaltenes. The second most important attribute of any chemical compound is its molecular structure and, as a prerequisite to that information, molecular weight.

Often, measurements at a particular length scale were extrapolated to other length scales without regard to direct measurements from other laboratories at that length scale. ” However, asphaltene science is too complex for a single laboratory to measure everything there is to know. This difficulty has been exacerbated by the existence of simple, low cost measurements that consistently generate the wrong answer. Improper asphaltene molecular weight determination via vapor pressure osmometry comes to mind.

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