By Peter Day
This necessary quantity brings jointly for the 1st time a variety of his articles on a majority of these subject matters, grouped in keeping with subject matter. every one workforce is prefaced by means of a quick advent for the overall reader, placing the articles into their context within the evolution of the topic and describing the highbrow conditions within which every one venture used to be conceived and done.
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Additional resources for MOLECULES INTO MATERIALS: CASE STUDIES IN MATERIALS CHEMISTRY - MIXED VALENCY, MAGNETISM AND SUPERCONDUCTIVITY
Mod. , 1942, 14, 204. la Walsh, J.. 1953, 2260. la Lewis, Nyholm. and Smith, J . , 1961, 4597. 14 Gray and Ballhausen, J . Amer. Chem. , 1963, 85, 260. Is (a) Farrington. J . Amer. Chem. SOL, 1952, 74, 966; (b) Matsuo, J . Chem. Japan, 1961, 83, 1330; (c) Barnes and Hume, J . Phys. , 1963, 67, 526. I* Foster and Hammick, J . , 1964, 2685. I’ Foster, Tvans. , 1963, 59, 1069. 18 Reid and Mulliken, J. Amer. Chem. , 1968, 76, 3869. , BUNOAY,SIRPOLK. 13 Reprinted from THEJ O U R N A L OF CHEMICAL PHYSICS, Vol.
3 Jnrgensen, Mot. , 1962, 5, 271. 4 Barnes, Paper. , p. 89. 6 Hanic, Acla Crvst.. 1959, 12,739; Hanic and Cakajdova, ibid.. 11. 610. 7 Dainton. I . 1952. 1533. 8 Oxidation Potentials,” Prentice-Hall, N. J . , 1952. 9 Latimer; Jorgensen, Absorption Spectra and Chemical Bonding in Complexes,” Pergamon, Oxford, 1962, ‘ p. 196. , Mitchell and Williams, J . , 1960, 1912. l1 Mulliken, J . Chem. , 1935, 3, 720; Rev. Mod. , 1942, 14, 204. la Walsh, J.. 1953, 2260. la Lewis, Nyholm. and Smith, J . , 1961, 4597.
Phys. 39, 116 (1963). 20 399 Molecules into Materials SPECTRA OF TETRAHALIDE COMPLEXES interpreting the crystal spectra of CuCL2- both because the weak shoulders of interest are not very well resolved and because it is difficult to make crystals of CszZnCL homogeneously doped with the flattened CuCL2- ion. 5 kK in CuCh2- and CuBraZ- as 2B2(2T2 in T d ) is substantiated by a number of arguments. 15 kK for 2T1. The splitting of orbital 312 is thus more dependent on molecular geometry than tl, a conclusion quite consistent with the former's bonding character.