Organic Reaction Mechanisms 2001: An annual survey covering by A. C. Knipe

By A. C. Knipe

This annual sequence on natural response mechanisms study offers concise, accomplished assurance of the year's literature in addition to discussions of significant effects, each one quantity is commonly referenced to earlier volumes and first journals.

This the 37th e-book within the sequence will survey examine on natural response mechanisms defined within the literature among December 1999 to November 2000.

As in prior volumes new mechanisms for the synthesis of every kind of natural compounds should be integrated in addition to such mechanisms as addition and removing reactions, nucleophilic and electrophilic fragrant substitutions and molecular arrangements.

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The mechanism has been further probed by kinetic studies in the presence of cationic and anionic surfactants. The kinetics of the oxidation of substituted benzaldehydes by benzyltrimethylammonium dichloroiodate, in the presence of zinc chloride, are explained in terms of the intermediacy of [PhCH2 NMe3 ]+ [IZn2 Cl6 ]− . 247 Ebselen [83a, 2-phenylbenzisoselenazol-3(2H )-one] acts as a chemoselective oxygen-transfer catalyst in the conversion of aromatic aldehydes to arenecarboxylic acids by t-butyl hydroperoxide,248 with minimal formation of Baeyer–Villiger product, apparently because of steric hindrance in the actual oxidizing species (83b).

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