Physical chemistry, Edition: 3rd ed by Gilbert William Castellan

By Gilbert William Castellan

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The coefficient of thermal expansion ex is defined by ex = (I/ V)(ilV/8 T)p ' Using the equation of state, compute the value of ex for an ideal gas. The coefficient of compressibility K is defined by K = - (1/V)(8 V/8ph . Compute the value of K for an ideal gas. For an ideal gas, express the deriv<:\tive (8p/8 T)v in terms of ex and K. Consider a gas mixture in a 2 dm3 flask at 27 DC. For each mixture calculate the partial pressure of each gas, the total pressure, and the composition of the mixture in mole percent.

32) allows the calculation of the partial pressure of any gas in a mixture from the mole fraction of that gas and the total pressure of the mixture. Two things should be noted about Eq. 32) : first, if either molar concentrations or mole ratios had been used, the final result would not be as simple an expression as Eq. 32) ; second, examination of the steps leading to Eq. 32) shows that it is not restricted to a mixture of three gases ; it is correct for a mixture containing any number of gases.

80665 m/s 2 . What is the mass of helium in the container ? 28 E m p i r i c a l P ro p e rt i es of G ases ¥ Vacuum 1 F i g u re 2 . 0 cm 3 . 42 mm. 3 5 mm. 2 DC. 3. a) What is the mass of helium in the system ? b) What is the volume of bulb 1 ? 03 m 3 (exactly), and To = 300 K (exactly). Compute the " gas-constant," the "Avogadro constant," and the masses of a " mole " of hydrogen atoms and oxygen atoms. The coefficient of thermal expansion ex is defined by ex = (I/ V)(ilV/8 T)p ' Using the equation of state, compute the value of ex for an ideal gas.

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